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Whilst rules and legislation are subject to change at present Cars or vans (not exceeding 3.5 tonnes gross vehicle weight) which emit 75g/km or less of CO2 and that meet the Euro 5 standard for air quality qualify for a 100% discount on the Congestion Charge, in practice that is likely to be either an electric or hybrid vehicle as conventionally fuelled petrol or diesel vehicles have yet to reach this threshold.
Latest details can be found here: https://tfl.gov.uk/modes/drivi...